Makine Mühendisliği Bölümü Koleksiyonu

Permanent URI for this collectionhttps://hdl.handle.net/20.500.11779/1944

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Browsing Makine Mühendisliği Bölümü Koleksiyonu by Author "Boztemur, B."

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    Citation - WoS: 6
    Citation - Scopus: 6
    Computational Alloy Design, Synthesis, and Characterization of Wmonbvcrx Refractory High Entropy Alloy Prepared by Vacuum Arc Melting
    (Elsevier Ltd, 2024) Alkraidi, A.B.N.; Mansoor, M.; Boztemur, B.; Gökçe, H.; Kaya, F.; Yıldırım, C.; Öveçoğlu, M.L.
    Prior investigations have demonstrated enhanced mechanical properties, such as hardness and wear resistance, through high-entropy alloy designs that contain refractory metals. We propose the WMoNbVCrx alloy phase space as a single-phase BCC-structured, hard, and refractory high-entropy alloy for the first time. The WMoNbVCrx alloy (x = 0, 0.25, 0.5, 0.75, and 1) system is investigated computationally through CALPHAD and DFT for the equimolar and non-equimolar compositional phase spaces and synthesized through vacuum arc melting. The DFT calculations demonstrated the excellence of specific non-equimolar compositional spaces. It was found that stoichiometries rich in W and poor in V are exceptionally hard, while those rich in V and poor in W demonstrate unprecedented toughness, as determined by the ductility descriptor (Pugh's Ratio). The computational analysis shows the significance of microstructures that contain both (W-rich and W-poor) solid solution, where a synergy between hardness and toughness is created. Our experimental synthesis using vacuum arc melting demonstrated the possibility of successfully producing these alloys with W-rich (dendritic) and W-poor (interdendritic) solid solution regions, starting from elemental powders. The introduction of chromium (Cr) resulted in enhanced microhardness and wear resistance. The peak microhardness was attained when 0.5 moles of Cr were added, reaching 7.03 ±0.24 GPa, accompanied by the least wear volume loss. The produced alloys were found to align with the computationally predicted-designed alloys in terms of the hardness and Young's modulus trends that they follow. This comprehensive investigation underscores the synergistic application of CALPHAD and DFT techniques in the tailored design of novel high-entropy alloys, explaining their synthesis, structural correspondence, and the pivotal role of Cr in enhancing the mechanical properties of these alloys. © 2024 Elsevier B.V.
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    Citation - WoS: 1
    Mechanochemical Synthesis and Characterization of Nanostructured Erb4 and Ndb4 Rare-Earth Tetraborides
    (John Wiley and Sons Inc, 2024) Boztemur, B.; Kaya, F.; Derin, B.; Öveçoğlu, M.L.; Li, J.; Ağaoğulları, D.
    Rare-earth borides have become very popular in recent decades with high mechanical strength, melting point, good corrosion, wear, and magnetic behavior. However, the production of these borides is very challenging and unique. The production of ErB4 and NdB4 nanopowders via mechanochemical synthesis (MCS) is reported in this study first time in the literature. Er2O3 or Nd2O3, B2O3, and Mg initial powders are mechanically alloyed for different milling times to optimize the process. Rare-earth borides with MgO phases are synthesized, then MgO is removed with HCl acid. The nanostructured rare-earth tetraboride powders are analyzed using X-ray diffraction (XRD). Based on the XRD, ErB4 powders are produced successfully at the end of the 5 h milling. However, the NdB4 phase does not occur as the stoichiometric ratio, so the B2O3 amount is decreased to nearly 35 wt%. When the amount of B2O3 is decreased to 20 wt%, NdB4 and NdB6 phases are 50:50 according to the Rietveld analysis. However, a homogenous NdB4 phase is obtained with 30 wt% loss of B2O3. The average particle sizes of ErB4 and NdB4 powders are nearly 100.4 and 85.6 nm, respectively. The rare-earth tetraborides exhibit antiferromagnetic-to-paramagnetic-like phase transitions at 18 and 8.53 K, respectively. © 2024 The Author(s). Advanced Engineering Materials published by Wiley-VCH GmbH.